Following weeks of protests in opposition to a new law, Liu Xiaoming says the UK is "interfering" in China's affairs in Hong Kong.
China's ambassador was once summoned to the Foreign Office after telling the UK to maintain its "hands off Hong Kong and exhibit respect".
Liu Xiaoming was given a dressing down after accusing London of forgetting the territory is no longer a British colony, alleging that a "colonial mindset is still haunting the minds of some officers or politicians".
He added: "They forget about that Hong Kong has now back to the embrace of the motherland."
Mr Liu said the UK was "interfering" in China's affairs in Hong Kong and "should critically mirror on the consequences of its words and deeds".
He used to be informed his comments had been both "unacceptable and inaccurate" by using the Foreign Office's Permanent Under Secretary Sir Simon McDonald.
A declaration from the Foreign Office added: "The British government's function has been set out clearly by means of the foreign secretary and other ministers."
Mr Liu's feedback observe weeks of protests in Hong Kong against a controversial extradition bill.
Tensions have been raised considerably on Monday night when protesters stormed the territory's legislative council, rebel police responding with tear gas.
Foreign Secretary Jeremy Hunt said beforehand this week that his "heart goes out to humans who have to fight for their freedoms".
He said that he did now not assist violence "in any circumstances" however understood people's concerns about "changes that are taking place in Hong Kong".
Speaking at the Chinese embassy in central London, Mr Liu told reporters: "The UK authorities selected to stand on the wrong side. It has made inappropriate remarks not solely to intervene in inner affairs of Hong Kong however also to back up the violent law-breakers."
The ambassador added: "I would like to reiterate that Hong Kong is China's special administrative region; it is now not what it used to be under British colonial rule."
Police backyard the Legislative Council building in Hong Kong
Mr Hunt stated relations between the UK and China were "based on mutual respect".
The Conservative leadership contender tweeted: "Message to Chinese govt: desirable members of the family between nations are based totally on mutual admire and honouring the legally binding agreements between them. That is the great way to hold the fantastic relationship between the UK and China."
Asked about Britain's subsequent top minister - extensively anticipated to be former overseas secretary Boris Johnson - Mr Liu said he hoped the new government, due later this month, would chorus from interfering in Chinese affairs.
Mr Johnson stated he backed the humans of Hong Kong "every inch of the way".
He also advised China to proceed with the "one country, two systems" principle beneath which the territory has been ruled on the grounds that being surpassed returned to China by Britain in 1997.
Hong Kong police said on Thursday that they had arrested 18 people, which include 12 for a protest on the morning of 1 July that preceded the storming of the legislature.
Officers said 11 guys and one woman have been taken into custody over a "violent incident" that passed off close to the legislature and allegedly involved assaulting and obstructing police officers.
Offences are stated to encompass the possession of offensive weapons, illegal meeting and failing to elevate identification.
The other six humans were arrested for disrupting a public meeting on 30 June, police added.
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