Foreign Secretary Jeremy Hunt has said there is a chance the US and Iran could give up up at conflict unintentionally.
It comes after US Secretary of State Mike Pompeo cancelled the Moscow leg of his outing to Russia to talk about Iran's contemporary nuclear threat with Mr Hunt and his European counterparts in Brussels instead.
Speaking as he arrived for the talks, Mr Hunt said: "We are very concerned about the threat of a war happening by way of accident with an escalation that is unintended on both side.
"What we need is a duration of calm to make positive that every person is aware what the different aspect is thinking, and most of all we want to make sure we do not quit up putting Iran lower back on the path to renuclearisation.
"If Iran turns into a nuclear energy its neighbours are possibly to desire to emerge as nuclear powers. This is already the most unstable area in the world and this would be a huge step in the incorrect direction."
EU overseas coverage chief Federica Mogherini said Monday's talks would focal point on "how to continue to first-rate guide the full implementation of the nuclear deal".
Mr Pompeo will meet his Russian counterpart Sergei Lavrov and President Vladimir Putin in the Black Sea inn of Sochi as planned on Tuesday.
His alternate of direction comes after Saudi Arabia stated two of its tankers - one of which was once on its way to select up oil to take to the US - have been attacked on Sunday off the coast of the United Arab Emirates.
Iran's overseas ministry demanded in addition small print about what passed off and warned against any "conspiracy orchestrated by way of ill-wishers" and "adventurism via foreigners" to undermine the maritime region's steadiness and security.
It comes amid growing tensions between the US and Iran after Tehran threatened to make bigger its uranium enrichment if new and better terms beneath the 2015 nuclear deal had been no longer reached with world powers in 60 days.
President Hassan Rouhani issued the ultimatum on the one-year anniversary of Donald Trump's decision to withdraw America from the Obama-era settlement and reimposed sanctions.
Letters were sent to the closing signatories of the deal - Britain, China, the European Union, France and Germany.
Speaking alongside Mr Pompeo in London ultimate week, Mr Hunt stated there would be "consequences" for Iran if it reneged on its commitments beneath the deal.
The depth of the animosity between the two countries rears its head regularly
Mr Pompeo stated Iran had made quite a few statements on the be counted "to get the world to jump" and the US would wait and see what motion Tehran would "actually" take.
The threat also accompanied the US deployment of an aircraft provider and bomber project force to the Middle East after country wide security adviser John Bolton stated the US had obtained "clear indications" that Iran was getting ready to perhaps assault American forces in the region.
In an interview with CNBC at the weekend, Mr Pompeo said the US used to be now not seeking a war with Iran.
"In the tournament that Iran decided to come after an American pastime - whether that be in Iraq or Afghanistan or Yemen or any vicinity in the Middle East - we are organized to respond in an gorgeous way," he stated of the decision to dispatch the USS Abraham Lincoln Carrier Strike Group and a bomber assignment force to the Gulf.
"Our purpose is now not war," he added.
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